The Szabó Research Group


Selected Publications

For full list of publication [click]

S. J. T. Jonker§, R. Jayarajan§, T. Kireilis, M. Deliaval, L. Eriksson, K. J. Szabó*: Organocatalytic Synthesis of α-Trifluoromethyl Allylboronic Acids by Enantioselective 1,2-Borotropic Migration; J. Am. Chem. Soc. 2020, 142, 21254-21259. §Contributed equally.

Q.Wang§, M. Lübcke§, M. Biosca§, M. Hedberg, L. Eriksson, F. Himo*, K. J. Szabó*: Enantioselective Construction of Tertiary Fluoride Stereocenters by Organocatalytic Fluorocyclization; J. Am. Chem. Soc. 2020, 142, 20048-20057. §Contributed equally.

X. Jiang, D. Meyer, D. Baran, M. A. Cortés González, K. J. Szabó*: Trifluoromethylthiolation, Trifluoromethylation and Arylation Reactions of Difluoro Enol Silyl Ethers J. Org. Chem. 2020, 85, 8311–8319.

M. Lübcke, D. Bezhan, K. J. Szabó*: Trifluoromethylthiolation-Arylation of Diazocarbonyl Compounds by Modified Hooz Multicomponent Coupling. Chem. Sci. 2019, 10, 5990-5995.

M. A. Cortés Gonzáles; X. Jiang, P. Nordeman, G. Antoni, K. Szabó*: Rhodium-mediated 18F-oxyfluorination of diazoketones using fluorine-18-containing hypervalent iodine reagent.  J. Chem. Commun. 2019, 55, 13358-13361.

 J. Zhao, S. J. T. Jonker, D. N. Meyer, G. Schulz, C. D. Tran, L. Eriksson, K. J. Szabó*: Copper-Catalyzed Synthesis of Allenylboronic Acids. Access to Sterically Encumbered Homopropargylic Alcohols and Amines by Propargylboration. Chem. Sci. 2018, 9, 3305-3312.

 M. A. Cortes Gonzalez, P. Nordeman, A. Bermejo Gomez, D. N. Meyer, G. Antoni, M. Schou, K. J. Szabó*: [18F]Fluoro-benziodoxole: A no-carrier-added electrophilic fluorinating reagent. Rapid, simple radiosynthesis, purification and application for fluorine-18 labelling. Chem. Commun. 2018, 54, 4286-4289.

 M. Lübcke, W. Yuan, K. J. Szabó*: Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis. Org. Lett. 2017, 19, 4548-4551.

N. O. Ilchenko, M. Hedberg, K. J. Szabó*: Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine Reagents. An Efficient Method for 1,3-Oxyfluorination and   1,3-Difluorination. Chem. Sci. 2017, 8, 1056-1061.

D. Colin, K. J. Szabó*: Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis. J. Am. Chem. Soc. 2017, 139, 2-14. (Highlighted in Spotlights on Recent JACS Publications J. Am. Chem. Soc. 2017, 139, 1)

R. Alam, C. Diner, S. Jonker, K. J. Szabo*: Catalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids. Stereodivergent Synthesis up to Three Contiguous Stereocenters. Angew. Chem. Int. Ed. 2016, 55, 14417-14421. Highlited in Chemistry Views, Synfacts and Chemistry World.
W. Yuan, K. J. Szabó*: Rhodium-Catalyzed Oxy-Aminofluorination of Diazoketones with Tetrahydrofurans and NFSI. ACS Catal. 2016, 6, 6687-6691.
W. Yuan, L. Eriksson, K. J. Szabó*: Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-methylation of Diazocarbonyl Compounds.Angew. Chem. Int. Ed. 2016, 55, 8410-8415.
Y. Zhao, K. J. Szabó*: Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine and Oxetane Substrates. Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates. Angew. Chem. Int. Ed. 2016, 55, 1502-1506.
N. O. Ilchenko, M. A. Cortés, K. J. Szabó*: Palladium Catalyzed Iodofluorination of Alkenes using Fluoro-Iodoxole Reagent. ACS Catal. 2016, 6, 447-450.
R. Alam, T. Vollgraff, L. Eriksson, K. J. Szabó*: Synthesis of Adjacent Quaternary Stereocenters by Catalytic Asymmetric Allylboration. J. Am. Chem. Soc. 2015, 137, 11262-11265.
W. Yuan, K. J. Szabó*: Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent. Angew. Chem. Int. Ed. 2015, 15, 8533-8537.
A. Das, D. Wang, M.-C. Belhomme, K. J. Szabó*: Copper-Catalyzed Cross-Coupling of Allylboronic Acids with a-Diazoketones. Org. Lett. 2015, 17, 4754-4757. ACS Editors’ Choice 9/16/15
N. O. Ilchenko, B. O. A Tasch, K. J. Szabó: Mild Silver Mediated Geminal Difluorination of Styrenes by Air and Moisture Stable Fluoroiodane Reagent. Angew. Chem. Int. Ed. 2014, 53, 12897-12901

T. S. N. Zhao, Y. Yang, T. Lessing, K. J. Szabó: Borylation of Propargylic Substrates by Bimetallic Catalysis. Synthesis of Allenyl, Propargylic and Butadienyl Bpin Derivatives. J. Am. Chem. Soc. 2014, 136, 7563-7566.

R. Alam, A. Das, G. Huang, L. Eriksson, F. Himo, K. J. Szabó: Stereoselective Allylboration of Imines and Indoles under Mild Conditions. In Situ E/Z Isomerization of Imines by Allylboroxines. Chem. Sci. 2014, 5, 2732-2738

J. M. Larsson, K. J. Szabó: A Mechanistic Investigation of the Palladium-Catalyzed Synthesis of Allylic Silanes and Boronates from Allylic Alcohols. J. Am. Chem. Soc. 2013, 135, 443-455.

M. Raducan, R. Alam, K. J. Szabó: Palladium-Catalysed Synthesis and Isolation of Functionalized Allylboronic Acids. Selective, Direct Allylboration of Ketones. Angew. Chem. Int. Ed. 2012, 51, 13050-13053.
R. Alam, L. T. Pilarski, E. Pershagen: Stereoselective Intermolecular Allylic C-H Trifluoroacetoxylation of Functionalized Alkenes. J. Am. Chem. Soc. 2012, 134, 8778-8781.
P. G. Janson, I. Ghoneim, N. O. Ilchenko: Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes. Org. Lett. 2012, 14, 2882-2885.
N. Selander, J. R. Paasch, K. J. Szabó: Palladium-Catalyzed Allylic C−OH Functionalization for Efficient Synthesis of Functionalized Allylsilanes. J. Am. Chem. Soc. 2011, 133, 409-411.
N. Selander, K. J. Szabó: Catalysis by Palladium Pincer Complexes. In special issue “Frontiers in Transition Metal Catalyzed Reactions”. Chem. Rev. 2011, 111, 2048-2076.