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1991-1995
Á. Zsigmond, F. Nothieisz, Z. Szegletes and J. E. Bäckvall, “Aerobic Oxidations on Metal Macrocycles Encapsulated on Zeolites ” Stud. Surf. Sci. Catal. 1995 , 94 , 728.
A. Castaño, A. Aranyos, K. Szabo and J. E. Bäckvall, “Nucleophilic Attack on (π-allyl)palladium Complexes – Factors Determining Attack at Central versus Terminal Carbon ” Angew. Chem. Int. Ed. 1995 , 34 , 2551.
M. Rönn, J. E. Bäckvall and P. G. Andersson, “Palladium(II)-Catalyzed Intramolecular Cyclization Using Molecular Oxygen as Reoxidant ” Tetrahedron Lett. 1995 , 36 , 7749.
E. S. M. Persson and J. E. Bäckvall, “The Effect of Solvent and Copper(I) Precursor on the Regioselectivity in the Cross-Coupling Reaction of Allylic Acetates with Preformed Mono- and Dibutylcuprates ” Acta Chem. Scand. 1995 , 49 , 899.
M. van Klaveren, E. S. M. Persson, D. M. Grove, J. E. Bäckvall and G. van Koten, “Chiral Arenethiolatocopper(I) Catalyzed Substitution Reactions of Acyclic Allylic Substrates with Butyl Grignard Reagents ” Tetrahedron Lett. 1995 , 36 , 3059.
J. E. Bäckvall, Y. I. M. Nilsson and R. G. P. Gatti, “Stereochemistry and Mechanism of Chloropalladation of Acetylenes ” Organometallics 1995 , 14 , 4242.
H. Pettersson-Fasth, S. W. Riesinger and J. E. Bäckvall, “An Enantioselective Route to cis – and trans -2-Hydroxymethyl-5-Alkyl Pyrrolidines ” J. Org. Chem. 1995 , 60 , 6091.
E. B. Koroleva, J. E. Bäckvall and P. G. Andersson, “Palladium-Catalyzed Stereoselective Synthesis of Bicyclic Tetrahydropyrans ” Tetrahedron Lett. 1995 , 36 , 5397.
H. Pettersson‑Fasth, A. Gogoll and J. E. Bäckvall, “Diastereoselectivity in the OsO4-Catalyzed Dihydroxylation of 5-(p-Toluenesulfonamido)-3-hexene-2-ol Derivatives ” J. Org. Chem. 1995 , 60 , 1848.
A. Castaño and J. E. Bäckvall, “Allylsilanes as Carbon Nucleophiles in Intramolecular Pd(II)-Catalyzed 1,4-Addition to Conjugated Dienes ” J. Am. Chem. Soc. 1995 , 117 , 560.
C. M. G. Löfström, A. M. Ericsson, L. Bourrinet, S. K. Juntunen and J. E. Bäckvall, “Functionalization of 2-Phenylsulfonyl 1,3-Dienes via Cyclopropanation and Epoxidation. Synthesis of Oxabicyclic Systems vi BF3 -Induced Rearrangement of Epoxide Derivatives ” J. Org. Chem. 1995 , 60 , 3586.
E. S. M. Persson, M. van Klaveren, D. M. Grove, J. E. Bäckvall and G. van Koten, “ortho -Chelating Arenethiolatocopper(I) Complexes as Versatile Catalysts in the Regioselective Cross-Coupling of Allylic Derivatives with n -BuMgI. A n example of Reversed Reactivity of Leaving Groups. ” Chem. Eur. J. 1995 , 1 , 351.
Y. I. M. Nilsson and J. E Bäckvall “Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) ” Encyclopedia of Reagents for Organic Synthesis, Ed. L. A. Paquette, Wiley Interscience, 1995 , Vol 1, pp 431-32.
R. G. P. Gatti and J. E. Bäckvall, “Bis(triphenylphosphine)palladium(II) Acetate ”, Encyclopedia of Reagents for Organic Synthesis, Ed. L. A. Paquette, Wiley Interscience, 1995 , vol 1, pp 619-21.
J. E. Bäckvall and D. Tanner, “Palladium-Mediated Synthesis of Alkaloids” , review in Studies in Natural Products Chemistry”, Ed. Atta-Ur-Rahman, Elsevier, 1995 , Vol 16, pp 415-452.
M. van Klaveren, E .S .M. Persson, D. M. Grove, J. E. Bäckvall and G. van Koten, “The use of Ortho‑chelating Arenthiolate Non-transferable Groups in the Copper(I)-Catalyzed Selective α or γ Substitution of Acyclic Allylic Substrates with Grignard Reagents ” Tetrahedron Lett. 1994 , 35 , 5931.
J. E. Bäckvall and A. Ericsson, “Palladium-Catalyzed Regioselective Addition of Thiophenol to Conjugated Enynes. A Novel Route to 2-(Phenylsulfinyl)- and 2-(Phenylsulfonyl)-1,3-Dienes ” J. Org. Chem. 1994 , 59 , 5850.
J. E. Bäckvall, Y. I. M. Nilsson, P. G. Andersson, R. G. P. Gatti and J. Wu, “Carbon-Carbon Bond Formation in Palladium(II)-Catalyzed Intramolecular 1,4-Oxidation of Conjugated Dienes ” Tetrahedron Lett. 1994 , 35 , 5713.
A. Gogoll, J. Örnebro, H. Grennberg and J. E. Bäckvall, “Mechanism of Apparent p-Allyl Rotation in ( π-Allyl)palladium complexes with Bidentate Nitrogen Ligands ” J. Am. Chem. Soc. 1994 , 116 , 3631.
P. G. Andersson, Y. I. M. Nilsson and J. E. Bäckvall, “Palladium-Catalyzed Spirocyclization ” Tetrahedron 1994 , 50 , 559.
H. Grennberg, V. Simon and J. E. Bäckvall, “Evidence for a (π-Allyl)palladium Intermediate in the quinone-Based Palladium-Catalyzed Allylic Acetoxylation ” J. Chem. Soc. Chem. Commun. 1994 , 265.
A. M. Ericsson, N. A. Plobeck and J. E. Bäckvall, “Stereoselective Synthesis of Vinylcyclopropanes from 2-Phenylsulfonyl-1,3-cyclohexadienes and Ketone Enolates or Nitrile Anions ” Acta Chem. Scand. 1994 , 48 , 252.
R. Chinchilla and J. E. Bäckvall, “Cycloadditions to Enamines”, review in “The Chemistry of Functional Groups: The Chemistry of Enamines “, Ed. S. Patai and Z. Rappoport, Wiley, 1994 , 993.
J. E. Bäckvall, E. S. M Persson and A. Bombrun, “Regiocontrol in Copper-Catalyzed Cross Coupling of Allylic Chlorides with Aryl Grignard reagents ” J. Org. Chem. 1994 , 59 , 4126.
J. E. Bäckvall, “Stereocontrol in Palladium-Catalyzed Reactions”, review in “Organometallic Reagents in Organic Synthesis ”, Ed. J. H. Batesson and M. B. Mitchell, Academic Press, 1994 , pp 81-97.
G-Z. Wang, U. Andreasson and J. E. Bäckvall, “Aerobic Oxidation of Secondary Alcohols via Ruthenium-Catalyzed Hydrogen Transfer involving a New Triple Catalytic System ” J. Chem. Soc., Chem. Commun. 1994 , 1037.
U. Karlsson, G-Z. Wang and J. E. Bäckvall, “Ruthenium-Catalyzed Oxidation of Secondary Alcohols by MnO2 ” J. Org. Chem. 1994 , 59 , 1196.
Á. Zsigmond, F. Nothieisz, M. Bartok and J. E. Bäckvall, “Selective Oxidation of Alkenes on a Zeolite Supported Iron Phthalocyanine catalyst ” Stud. Surf. Sci. Catal. 1993 , 78 , 417.
J. E. Bäckvall and U. Andreasson, “Ruthenium-Catalyzed Isomerization of Allylic Alcohols to Saturated Ketones ” Tetrahedron Lett. 1993 , 34 , 5459.
J. E Bäckvall , A. M. Ericsson, S. K. Juntunen, C. Najera and M. Yus, “Selective Epoxidation of 2-Phenylsulfonyl 1,3-Dienes. One-Pot Procedure for Regioselective Preparations of 2-Phenylsulfonyl 1,3-Diene Monoepoxides from 1,3-Dienes ” J. Org. Chem. 1993 , 58 , 5221.
J. E. Bäckvall, C. Löfström, S. K. Juntunen and M. Mattson, “Regioselective Cyclopropanation of 2-Phenylsulfonyl 1,3-Dienes ” Tetrahedron Lett. 1993 , 34 , 2007.
J. E. Bäckvall, R. Gatti and H. E. Schink, “Enzyme and Palladium Catalysis as a Powerful Combination in Asymmetric Transformations of meso-2-Alken-1,4-diol Derivatives. Application to Enantiodivergent Synthesis of (R)- and (S)-(2,4-Cycloalkadienyl)acetic Acids ” Synthesis (Feature Article) 1993 , 343.
J.E. Bäckvall, “Recent Advances in Organopalladium Chemistry “, review in “Organic Synthesis via Organometallics (OSM 4)”, Eds. D. Enders, H.J. Gais, H.J. Keim, Vieweg, 1993 , pp 165-174.
H. Grennberg and J. E. Bäckvall, “Aerobic Palladium-Catalyzed 1,4-cis-Diacetoxylation and 1,4-cis-Chloroacetoxylation of 1,3-Cyclohexadiene by the use of a Tetra(dimethoxyphenyl)porphyrin ” J. Chem. Soc., Chem. Commun. 1993 , 1331.
Y. I. M. Nilsson, P. G. Andersson and J. E. Bäckvall, “Example of Thermodynamic Control in Palladium-Catalyzed Allylic Alkylation. Evidence for Palladium‑Assisted C-C Bond Cleavage ” J. Am. Chem. Soc. 1993 , 115 , 6609.
H. Grennberg, A. Gogoll and J. E. Bäckvall, “Acid-Induced Transformation of Palladium(0)-Benzoquinone Complexes to Palladium(II) and Hydroquinone ” Organometallics 1993 , 12 , 1790.
H. Grennberg and J. E. Bäckvall, “Iron Phthalocyanine, Fe(Pc), as Catalyst for the Aerobic Oxidation of Hydroquinone to 1,4-Benzoquinone. A Simple Test for Catalytic “Oxidase” Activity ” Acta Chem. Scand. 1993 , 47 , 506.
H. Grennberg, S. Fazon and J. E. Bäckvall, “Use of a Cobalt Tetrakis(hydroquinone)porphyrin for Efficient Electron Transfer in Aerobic Palladium-Catalyzed 1,4-Diacetoxylation of 1,3-Cyclohexadiene ” Angew. Chem. Int. Ed. 1993 , 32 , 263.
J. E. Bäckvall, K. L. Granberg, P. G. Andersson, R. Gatti and A. Gogoll, “Stereocontrolled Lactonization Reactions via Palladium-Catalyzed 1,4-Addition to Conjugated Dienes ” J. Org. Chem. 1993 , 58 , 5445.
J. E. Bäckvall, R. L. Chowdhury, U. Karlsson and G.-Z. Wang, “Ruthenium-Catalyzed Hydrogen Transfer Reactions and Their Application to Oxidation of Alcohols and Reduction of Ketones and Imines”, review in “Perspective in Coordination Chemistry ” (Eds A. F. Williams, C. Floriani, A. E. Merbach) Verlag Helvetica Chimica Acta, Basel, 1992 , pp 463-486.
P. G. Andersson and J. E. Bäckvall, “Palladium-Catalyzed Tandem Cyclization of 4,6- and 5,7-Dienamides. A new route to the Pyrrolizidine and Indolizidine Alkaloids ” J. Am. Chem. Soc. 1992 , 114 , 8696.
R. Chinchilla and J. E. Bäckvall, “Cycloadditions of 2-Nitro 1,3-Dienes to Enamines. Synthesis of Unsaturated Nitroketones and Diels-Alder Adducts via [4+2] Heterocycloadditions ” Tetrahedron Lett. 1992 , 33 , 5641.
G.-Z. Wang and J. E. Bäckvall, “Ruthenium-Catalysed Transfer Hydrogenation of Imines by Propan-2-ol ” J. Chem. Soc., Chem. Commun. 1992 , 980.
J. E. Bäckvall, C. Löfström, M. Maffei and V. Langer, “Asymmetric Induction in [4+2] Cycloadditions of Chiral Enamines to 2-Phenylsulfonyl 1,3-Dienes ” Tetrahedron Lett. 1992 , 33 , 2417.
G‑Z. Wang and J. E. Bäckvall, “Ruthenium-Catalyzed Oxidation of Alcohols by Acetone ” J. Chem. Soc., Chem. Commun. 1992 , 337.
H. Pettersson, A. Gogoll and J. E. Bäckvall, “Epoxidation of 5-Tosylamido-3-hexen-2-ol Derivatives. Stereochemical Assignment of Product Configuration by NMR and Molecular Mechanics Studies ” J. Org. Chem. 1992 , 57 , 6025.
H. E. Schink and J. E. Bäckvall, “Synthesis of (+)-(E)-(2S,5R)-5-Acetoxy-hexen-2-ol via Enantioselective Enzymatic Hydrolysis. An Enantiodivergent PalladiumCatalyzed Route to (+)- and (-)-cis-2-Methyl-5-hexanolide ” J. Org. Chem. 1992 , 57 , 1588. Correction: J. Org. Chem. 1992 , 57 , 6082.
J. E. Bäckvall, “Palladium-Catalyzed Intramolecular 1,4-Additions to Conjugated Dienes ” Pure Appl. Chem. 1992 , 64 , 429.
J. E. Bäckvall and P. G. Andersson, “Intramolecular Palladium-Catalyzed 1,4-Addition to Conjugated Dienes. Stereoselective Synthesis of Fused Tetrahydrofurans and Tetrahydropyrans ” J. Am. Chem. Soc. 1992 , 114 , 6374.
A. M. Ericsson, N. A. Plobeck, S. K. Juntunen and J. E. Bäckvall, “Stereoselective Synthesis of (3E,5E)-Diene-2-ones and (2E,4E)-Dienals via 2-Phenylsulfonyl 1,3-Dienes ” Tetrahedron Lett. 1992 , 33 , 131.
J. E. Bäckvall, F. Bökman and M. R. A. Blomberg, “Metallaoxetanes as Possible Intermediates in Metal-Promoted Deoxygenation of Epoxides and Epoxidation of Olefins ” J. Am. Chem. Soc. 1992 , 114 , 534.
K. L. Granberg and J. E. Bäckvall, “Isomerization of (π-Allyl)palladium Complexes via Nucleophilic Displacement by Pd(0). A Common Mechamism in Pd(0)-Catalyzed Allylic Substitution ” J. Am. Chem. Soc. 1992 , 114 , 6858. Correction: J. Am. Chem. Soc. 1994 , 116 , 10853.
J. E. Bäckvall, U. Karlsson and R. Chinchilla, “Synthesis of 2-Nitro 1,3-Dienes. Useful Intermediates in the Preparation of Unsaturated 1,4-Dicarbonyl Compounds ” Tetrahedron Lett. 1991 , 32 , 5607.
H. Grennberg, V. Langer and J. E. Bäckvall, “Structure and Reactivity of cis- and trans-Bis-[(5-Carbomethoxy-η3 -(1,2,3)-cyclohexenyl)palladium chloride]. Evidence for a (σ-Allyl)palladium Intermediate in the cis-Migration of Acetate from Palladium to Coordinated π-Allyl ” J. Chem. Soc., Chem. Commun. 1991 , 1190.
R. L. Chowdhury and J. E. Bäckvall, “Efficient Ruthenium-Catalyzed Transfer Hydrogenation of Ketones by iso-Propanol ” J. Chem.Soc., Chem. Commun. 1991 , 1063.
P. G. Andersson and J. E. Bäckvall, “Synthesis of Furanoid Terpenes Using an Efficient Palladium-Catalyzed Cyclization of 4,6-Dienols ” J. Org. Chem. 1991 , 56 , 5349.
H. Grennberg, A. Gogoll and J. E. Bäckvall, “Use of Sulfoxides as Cocatalysts in the Palladium-Quinone-Catalyzed 1,4-Diacetoxylation of 1,3-Dienes. An Example of Ligand Accelerated Catalysis ” J. Org. Chem. 1991 , 56 , 5808.
H. E. Schink, H. Pettersson and J. E. Bäckvall, “Stereocontrolled Epoxidation of Cycloheptene Derivatives in the Palladium-Catalyzed Route to Tropane Alkaloids. Total Synthesis of Scopine and Pseudoscopine ” J. Org. Chem. 1991 , 56 , 2769.
J. E. Bäckvall and P. G. Andersson, “Stereocontrolled Oxaspirocyclization of Conjugated Dienes via Palladium Catalysis ” J. Org. Chem. 1991 , 56 , 2274.
N. Plobeck and J. E. Bäckvall, “Synthesis of (2E,4E)-Dienamides and (2E,4E)Dienoates from 1,3-Dienes via 2-Phenylsulfonyl 1,3-Dienes ” J. Org. Chem. 1991 , 56 , 4508.
J. E. Bäckvall, R. L. Chowdhury and U. Karlsson, “Aerobic Ruthenium-Catalyzed Oxidation of Alcohols via Multistep Electron Transfer ” J. Chem. Soc., Chem. Commun , 1991 , 473.
J. E. Bäckvall, P. G. Andersson, G. B. Stone and A. Gogoll, “Synthesis of (±)- a -and (±)-γ -Lycorane via a Stereocontrolled Organopalladium Route ” J. Org. Chem. 1991 , 56 , 2988.
J. E. Bäckvall, K. L. Granberg and A. Heumann, “On the Mechanism of Palladium(0)-Catalyzed Reactions of Allylic Substrates with Nucleophiles. Origin for the Loss of Stereospecificity ” Israel J. Chem. 1991 , 31 , 17.
M. Sellén, J. E. Bäckvall and P. Helquist, “Synthesis of Substituted Cyclic 1,3-Dienes via Selective 1,4-Elimination of Benzenesulfinic Acid from Allylic Phenyl Sulfones ” J. Org. Chem. 1991 , 56 , 835.
“π-Allylic Transition Metal Complexes by Oxidative Addition “, review in “Inorganic Reactions and Methods” Ed. J.J. Zuckerman, Verlag Chemie, pp 131-153, 1991 (with K. Zetterberg and B. Åkermark).
“π-Allylic Complexes from Allylic C-H Bond Cleavage in Olefins by Metal Complexes “, review in “Inorganic Reactions and Methods”, Ed. J. J. Zuckerman, Verlag Chemie, pp 123-132, 1991 (with K. Zetterberg and B. Åkermark).
C. Nájera, M. Yus, U. Karlsson, A. Gogoll and J. E. Bäckvall, “Nitroselenation of Conjugated Dienes. Preparation of 3,4-Epoxy-3-nitro-1-alkenes ” Tetrahedron Lett. 1990 , 31 , 4199.
J. E. Bäckvall, M. Sellén and B. Grant, “Regiocontrol in Copper-Catalyzed Grignard Reactions with Allylic Substrates ” J. Am. Chem. Soc. 1990 , 112 , 6615.
J. E. Bäckvall and N. A. Plobeck, “A New Synthesis of 6H-Pyrido(4,3-β)carbazoles Ellipticine and Olivacine via Cycloaddition of 2-Phenylsulfonyl-1,3-dienes to Indoles ” J. Org. Chem. 1990 , 55 , 4528.
J. E. Bäckvall, “Stereoselective Annulations via Palladium-Catalyzed Reactions ”, review in New J. Chem. 1990 , 14 , 447.
J. E. Bäckvall and P. G. Andersson, “Palladium-Catalyzed Stereocontrolled Intramolecular 1,4-Additions to Cyclic Dienes Involving Amides as Nucleophiles ” J. Am. Chem. Soc. 1990 , 112 , 3683.
J. E. Bäckvall, R. B. Hopkins, H. Grennberg, M. Mader and A. K. Awasthi, “Multistep Electron Transfer in Palladium-Catalyzed Aerobic Oxidations via a Metal Macrocycle-Quionon System ” J. Am. Chem. Soc. 1990 , 112 , 5160.
J. E. Bäckvall, H. E. Schink and Z. D. Renko, “A Stereocontrolled Organopalladium Route to 2.5-Disubstituted Pyrrolidine Derivatives. Application to the Synthesis of a Venom Alkaloid of the Ant Species Monomorium Latinode ” J. Org. Chem. 1990 , 55 , 826.
J. E. Bäckvall, K. L. Granberg and R. B. Hopkins, “Improved Palladium-Catalyzed 1,4-Halooacyloxylation and 1,4-Diacyloxylation of Conjugated Dienes ” Acta. Chem. Scand. 1990 , 44 , 492.
J. E. Bäckvall, S. K. Juntunen and O. S. Andell, “Synthesis of 2-(phenylsulfonyl)-1,3-cyclohexadiene ” Org. Synth. 1990 , 68 , 148 / Coll. Vol. 8, 540. skrivet på inbjudan av J.P. Freeman.
J. E. Bäckvall and J. O. Vågberg, “Stereoselective 1,4-Functionalizations of Conjugated Dienes: cis- and trans-1-Acetoxy-4-((dicarbomethoxy)methyl)-2-Cyclohexene ” Org. Synth. 1990 , 69 , 38 / Coll. Vol. 8, 5. skrivet på inbjudan av Editorn J.P. Freeman.
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