Some of the Martín-Matute group's publications are accessible via open access.
Publications 2017-
- Selective and Quantitative Functionalization of Unprotected α-Amino Acids Using a Recyclable Homogeneous Catalyst
Bermejo-López, A.; Raeder, M.; Martínez-Castro, E. Martín-Matute, B.*
Chem 2022, 8, 3302-3323.
DOI: 10.1016/j.chempr.2022.08.017 - Iron-Catalyzed Borylation of Propargylic Acetates for the Synthesis of Multisubstituted Allenyl boronates
Bermejo-López, A.; Kong, W.-J.; Tortajada, Pedro. J.; Posevins, D.*; Martín-Matute, B.*; Bäckvall, J.-E.*
Chem. Eur. J. 2022, e202203130.
DOI: doi.org/10.1002/chem.202203130 - Synthesis of α,γ-Chiral Trifluoromethylated Amines through the Stereospecific Isomerization of α-Chiral Allylic Amines
Garcia Vazquez, V; Martínez-Pardo, P.; Postole, A.; Inge, A.; Martín-Matute, B.*
Org. Lett. 2022, 24, 3867–3871.
DOI: 10.1021/acs.orglett.2c01436 - An Expedient Method for the Umpolung Coupling of Enols with Heteronucleophiles
García-Vázquez, V.; Carretero Cerdán, A., Sanz-Marco, A.; Bomez-Bengoa, E.; Martín-Matute, B.*
Chem. Eur. J. 2022, 28, e202201000.
DOI: 10.1002/chem.202201000 - Merging Directed C-H Activations with High-Throughput Experimentation: Development of Iridium-Catalyzed C-H Aminations Applicable to Late-Stage Functionalization
Weis, E.; Johansson, M.; Korsgren, P.; Martin Matute, B.*; Johansson, M. J.*
JACS Au, 2022, 2, 906–916.
DOI: 10.1021/jacsau.2c00039 - Electrochemical Proton Reduction over a Nickel Foam for Z-Stereoselective Semihydrogenation/deuteration of Functionalized Alkynes
Valiente, A.; Martínez-Pardo, P.#; Kaur, G.#; Johansson, J. M.; Martín-Matute, B.
ChemSusChem, 2022, 15, e202102221.
DOI: 10.1002/cssc.202102221 - Cover Feature: Electrochemical Proton Reduction over a Nickel Foam for Z-Stereoselective Semihydrogenation/deuteration of Functionalized Alkynes
Valiente, A.; Martínez-Pardo, P.#; Kaur, G.#; Johansson, J. M.; Martín-Matute, B.
ChemSusChem, 2022, DOI: https://doi.org/10.1002/cssc.202102519 - Late-stage amination of drug-like benzoic acids: Access to anilines and drug conjugates via directed iridium-catalyzed C−H activation
Weis, E.; Johansson, M. J.; Martín-Matute, B.
Chem. Eur. J. 2021, 27, 18188-18200.
DOI: 10.1002/chem.202103510 - Selective Synthesis of Imines by Photooxidative Amine Cross-Condensation Catalyzed by PCN-222(Pd)"
Bermejo-Lopez, A.; Carrasco, S.; Tortajada, P.; Kopf, K.; Sanz-Marco, A.; Hvid, M. ; Lock, N.; Martin-Matute, B.
ACS Sustainable Chem. Eng. 2021, 9, 14405–14415.
DOI: 10.1021/acssuschemeng.1c04389 - Sustainable Chemistry and Engineering in Pharma
Martín-Matute, B.; Meier, m. A. R.; Métro, T.-X., Koening, S. G.; Sneddon, H. F.; Sudarsanam, P.; Watts, P.
ACS Sustainable Chem. Eng. 2021, 9, 13395 - 13398.
DOI: 10.1021/acssuschemeng.1c06526 - Iridium-Catalyzed C-H Methylation ad d3-Methylation of Benzoic Acids with Applications to Late-Stage Functionalizations
Weis, E.; Hayes, M. A.; Johansson, M. J.; Martín-Matute, B.
iScience 2021, 24, 102467.
DOI: 10.1016/j.isci.2021.102467 - Unraveling the Mechanism of the Ir(III)-Catalyzed Regiospecific Synthesis of alpha-Chlorocarbonyl Compounds from Allylic Alcohols Man Li, M.; Sanz-Marco, A.; Martinez-Erro, S.; García-Vázquez, V.; Mai B. K.; Fernández-Gallardo, J.; Himo, F.; Martín-Matute, B.
Chem. Eur. J. 2020, 26, 14978 - 14986. Hot Paper
DOI: 10.1002/chem.202002845 - Ir(III)-Catalyzed Selective ortho-Monoiodination of Benzoic Acids with Unbiased C-H Bonds
Weis, E.; Johansson, M. J.; Martín-Matute, B.
Chem. Eur. J. 2020, 26, 10185 - 10190. Hot Paper
DOI: 10.1002/chem.202002204 (Open access)
This article also appears in: Hot Topic: C-H Activation
Cover picture DOI: 10.1002/chem.202003296 - Stereospecific Isomerization of Allylic Halides via Ion Pairs with Induced Non-Covalent Chirality
Martinez-Erro, S.#; Garcia-Vazquez, V.#; Sanz-Marco, A.; Martín-Matute, B.
Org. Lett. 2020, 22, 4123–4128.
DOI: 10.1021/acs.orglett.0c01200 (Open access) - An Umpolung Strategy to React Catalytic Enols with Nucleophiles
Sanz-Marco, A.; Martinez-Erro, S.; Pauze, M.; Gomez-Bengoa, E.; Martín-Matute, B.
Nature Commun. 2019, 10, 524450
Top 50 most read Nature Communications articles in chemistry and materials sciences published in 2019
DOI: doi:10.1038/s41467-019-13175-5 (Open Access) - Base-Catalyzed [1,n]-Proton Shifts in Conjugated Polyenyl Alcohols and Ethers
Molleti, N.#; Martinez-Erro, S.#; Carretero Cerdan, A.; Sanz-Marco, A.; Gomez-Bengoa, E.; Martín-Matute, B.
ACS Catalysis, 2019, 9, 9134-9139.
DOI: 10.1021/acscatal.9b02478 (Open Access)
- A Fast and Robust Synthesis of Metalated PCN-222 and their Catalytic Performance in Cycloaddition Reactions with CO2
Carrasco, S.; Sanz-Marco, A.; Martin-Matute, B.
Organometallics 2019, 38, 3429-3435
DOI: 10.1021/acs.organomet.9b0027 (Open access)
Invited for the Special Issue "Organometallic Chemistry within Metal-Organic Frameworks" - Metal-Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective
Pascanu, V.; González Miera, G.; Inge, A. K.; Martín-Matute, B.
J. Am. Chem. Soc. 2019, 141, 7223-7234.
DOI: 10.1021/jacs.9b00733 (Open Access) - Aerobic Homocoupling of Arylboronic Acids Catalyzed by Regenerable Pd(II)@MIL-88B-NH2(Cr)
Valiente, A.; Carrasco, S.; Sanz-Marco, A.; Tai, C.-W.; Bermejo Gómez, A.; Martín-Matute, B.
ChemCatChem. 2019, 11, 3933–3939.
DOI: 10.1002/cctc.201900556 (Free Access)
Invited for the special issue “Women of Catalysis” - Hydrazine-free Facile Synthesis of Palladium-Tetrakis(Triphenylphosphine)
Carrasco, S.; Martín-Matute, B.
Eur. J. Inorg. Chem. 2019, 1951-1955.
DOI: 10.1002/ejic.201900060 - Nonclassical Mechanism in the Cyclodehydration of Diols Catalyzed by a Bifunctional Iridium Complex
González Miera, G.#; Bermejo López, A.#; Martínez-Castro, E.; Nörrby, P.-O.; Martín-Matute, B.
Chem. Eur. J. 2019, 25, 2631-2636.
Hot Paper
DOI: 10.1002/chem.20180546 (Open access) - Luminescence properties of a family of lanthanide metal-organic frameworks
Abdelhamid, H. N.; Wilk-Kozubek, M.; El-Zohry, A. M.; Bermejo Gomez, A.; Valiente, A. Martin-Matute, B. Mudring, A.-V.; Zou, X.
Microporous and Mesoporous Materials, 2019, 279, 400-406.
DOI: 10.1016/j.micromeso.2019.01.024 - Probing the Evolution of Palladium Species in Pd@MOF Catalysts during the Heck Coupling Reaction: An Operando X-ray Absorption Spectroscopy Study
Yuan, N.;# Pascanu, V.;# Huang, Z.; Valiente, A.; Heidenreich, N.; Leubner, S.; Inge, A. K.; Gaar, J.; Stock, N.; Persson, I.; Martín-Matute, B.; Zou, X.
J. Am. Chem. Soc. 2018, 140, 8206–8217.
DOI: 10.1021/jacs.8b03505 (Open access) - Selective Synthesis of Unsymmetrical Aliphatic Acyloins through Oxidation of Iridium Enolates
Sanz-Marco, A.; Martinez-Erro, S; Martín-Matute, B.
Chem. Eur. J. 2018, 45, 11564-11567.
DOI: 10.1002/chem.201803117 (Open access) - "Base- and Additive-Free Ir-Catalyzed ortho-Iodination of Benzoic Acids: Scope and Mechanistic Investigations
Erbing, E.#; Sanz-Marco, A.#; Vázquez-Romero, A.; Malmberg, J.; Johansson, M.; Gómez-Bengoa, E.; Martín-Matute, B.
ACS Catal., 2018, 8, 920–925
DOI: 10.1021/acscatal.7b02987 (Open access)
# Authors contributed equally - Synthesis of α-Iodoketones from Allylic Alcohols through Aerobic Oxidative Iodination
Sanz-Marco, A.; Možina, S.; Iskra, J.; Martín-Matute, B.
Adv. Synth. Catal. 2018, 360, 3884-3888.
DOI: 10.1002/adsc.201800661
- Versatile Heterogeneous Palladium Catalysts for Diverse Carbonylation Reactions under Atmospheric CO Pressure
M. Vico Solano, G. González Miera, V. Pascanu, A. K. Inge and B. Martín-Matute*
ChemCatChem 2018, 10, 1089-1095.
DOI: 10.1002/cctc.201701439 - Acceptorless Alcohol Dehydrogenation: OH vs NH Effect in Bifunctional NHC−Ir(III) Complexes
Greco González Miera,‡ Elisa Martínez-Castro,‡ and Belén Martín-Matute
Organometallics, 2018, 37, 636-644
Invited to Special Issue: Organometallic Chemistry in Europe
DOI: 10.1021/acs.organomet.7b00220
Open Access - Homogeneous water oxidation by half-sandwich iridium(III)NHC complexes with pendant hydroxy and amino groups
B. Mahanti, G. González Miera, E. Martínez-Castro, M. Bedin; B. Martín-Matute, S. Ott, A. Thapper
ChemSusChem 2017, 10, 4616–4623.
DOI: 10.1002/cssc.201701370
Open Access - 2,2-Diododimedone: a mild electrophilic iodinating agent for the selective synthesis of alpha-iodoketones from allylic alcohols
Samuel Martinez-Erro,† Antonio Bermejo Gómez,† Ana Vázquez-Romero, Elis Erbing, and Belén Martín-Matute
Chem. Commun. 2017, 53, 9842-9845.
DOI: 10.1039/C7CC04823H (Open Access) - A water-stable lanthanide metal-organic framework for fluorimetric detection of ferric ions and tryptophan
Hani Nasser Abdelhamid,* Antonio Bermejo Gómez, Belén Martín-Matute, Xiaodong Zou
Microchim. Acta, 2017, 184, 3363–3371.
DOI: 10.1007/s00604-017-2306-0 (Open access) - Topological Transformation of a Metal-Organic Framework Triggered by Ligand Exchange
Greco González Miera, Antonio Bermejo Gómez, Peter J. Chupas, Belén Martín-Matute, Karena W. Chapman and Ana E. Platero-Prats
Inorg. Chem. 2017, 56, 4576–4583.
DOI: 10.1021/acs.inorgchem.7b00149 (Open Access)
- Catalyst Accessibility to Chemical Reductants in Metal-Organic Framework
Souvik Roy,‡ Vlad Pascanu,‡ Sonja Pullen, Greco González-Miera, Belén Martín-Matute and Sascha Ott
Chem. Commun. 2017, 53, 3257-3260.
DOI: 10.1039/C7CC00022G (Open Access)
Publications 2016
- Base-Catalyzed Stereospecific Isomerization of Electron-Deficient Allylic Alcohols and Ethers through Ion-Pairing
Martinez-Erro, S.‡;Sanz-Marco, A.‡;Bermejo Gómez, A.;Vázquez-Romero, A.; Ahlquist, M. S. G.; Martín-Matute, B.
J. Am. Chem. Soc. 2016, 138, 13408–13414.
DOI: 10.1021/jacs.6b08350
Open Access
- General, Simple and Chemoselective Catalysts for the Isomerization of Allylic Alcohols - The importance of the Halide Ligand
Erbing, E.;Vázquez-Romero, A.;Bermejo Gómez, A.;Platero-Prats, A. E.; Carson, F.;Zou, X.; Tolstoy, P.; Martín-Matute, B.
Chem. Eur. J. 2016,22, 15659–15663.
DOI: 10.1002/chem.201603825
Open Access
- Mild and Selective Catalytic Hydrogenation of the C=C Bond in α,β-Unsaturated Carbonyl Compounds Using Supported Palladium Nanoparticles
Nagendiran, A.; Pascanu, V.; Bermejo Gómez, A.; González Miera, G.;Tai, C.-W.; Verho, O.;Martín-Matute, B.; Bäckvall, Jan-E.
Chem. Eur. J. 2016, 22, 7184-7189.
DOI: 10.1002/chem.201600878
Open Access - Pascanu, V.; Carson, F.; Vico Solano, M.; Su, J.; Zou, X.; Johansson, M. J.; Martín-Matute, B.
"Selective Heterogeneous C−H Activation/Halogenation Reactions Catalyzed by Pd@MOF Nanocomposites"
Chem. Eur. J. 2016, 22, 3729-3737. Special issue "Women in Chemistry". Inside Cover. VIP paper.
DOI: 10.1002/chem.201502918
Open Access
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Publications 2015
- Platero-Prats, A. E.‡; Bermejo Gómez, A.‡; Chapman, K. W.; Martín-Matute, B.; Zou, X.
"Functionalising metal–organic frameworks with metal complexes: the role of structural dynamics"
CrystEngComm. 2015, 17, 7632-7635.
- Yao, Q.; Bermejo Gómez, A.; Su, J.; Pascanu, V.; Yun, Y.; Zheng, H.; Chen, H.; Liu, L.; Abdelhamid, H.; Martin-Matute, B.; Zou, X.
"A Series of Highly Stable Isoreticular Lanthanide Metal-Organic Frameworks with Expanding Pore Size and Tunable Luminescent Properties"
Chem. Mat. 2015, 27, 5332–5339.
DOI: 10.1021/acs.chemmater.5b01711
- Carson, F.; Martínez-Castro, E.; Marcos, R.; González Miera, G.; Jansson, K.; Zou, X.; Martín-Matute, B.
“Effect of the functionalisation route on a Zr–MOF with an Ir–NHC complex”
Chem. Commun. 2015, 51, 10864-10867.
DOI:10.1039/c5cc03934g
- Bartoszewicz, A.; González-Miera, G.; Marcos, R.; Norrby, P.-O.: Martín-Matute, B.
"Mechanistic Studies on the Alkylation of Amines with Alcohols Catalyzed by a Bifunctional Iridium Complex"
ACS Catal. 2015, 5,3704–3716.
DOI: 10.1021/acscatal.5b00645.
- Carson, F.; Pascanu, V.; Bermejo Gómez, A.; Zhang, Y.; Platero-Prats, A. E.; Zou, X.; Martín-Matute, B.
"Influence of the Base on Pd@MIL-101–NH2(Cr) as a Catalyst for the Suzuki–Miyaura Cross-Coupling Reaction"
Chem. Eur. J. 2015, 21, 10896-10902.
DOI: 10.1002/chem.201500843
Highlighted in Synfacts
- Martín-Matute, B.
"Transition Metal-Catalyzed Selective Formation of Carbon-Halogen and Carbon-Nitrogen Bonds"
Proceedings of the Symposium"CHEMISTRY: ANSWERS FOR A BETTER WORLD"
Anales de Quimica, 2015, 111(1), 60 (10, p 44). - Vázquez-Romero, A.; Bermejo Gómez, A.; Martín-Matute, B.
"An Acid- and Iridium-Catalyzed Tandem 1,3-Transposition / 3,1-Hydrogen Shift / Chlorination of Allylic Alcohols"
ACS Catalysis, 2015, 5, 708–714.
DOI: 10.1021/cs501618h
- Pascanu, V.; Bermejo Gómez, A.; Ayats, C.; Platero-Prats, A.; Carson, F.; Su, J.; Yao, Q.; Pericàs, M.; Zou, X.; Martín-Matute, B.
"A Double−Supported Silica – Metal-Organic Framework Palladium Nanocatalyst for Aerobic Oxidation of Alcohols under Batch and Continuous Flow Regimes"
ACS Catalysis, 2015, 5, 472–479.
DOI: 10.1021/cs501573c.
- Pascanu, V.; Hansen, P. R.; Bermejo Gómez, A.; Ayats, C.; Platero-Prats, A. E.; Johansson, M. J.; Pericàs, M. À.; Martín-Matute, B.
"Synthesis of highly functionalised biaryls via Suzuki-Miyaura cross-coupling catalysed by Pd@MOF under batch and continuous flow regimes"
ChemSusChem, 2015, 8, 123-130.
DOI: 10.1002/cssc.201402858
- Platero-Prats, A. E.,Bermejo Gómez, A.; Samain, L.;Zou, X.; Martín-Matute, B.
"The first one-pot synthesis of metal−organic frameworks multifunctionalised with two transition metal complexes"
Chem. Eur. J. 2015, 21, 861-866.
DOI: 10.1002/chem.201403909
Publications 2014
- Bermejo Gómez, A.; Holmberg, P.; Bäckvall, J.-E.; Martín-Matute, B.
"Transition metal-catalyzed redox isomerization of codeine and morphine in water"
RSC Advances, 2014, 4, 39519-39522. DOI: 10.1039/C4RA07735K
- Bermejo Gómez, A.; Ahlsten, N.; Platero-Prats, A. E.; Martín-Matute, B.
"Synthesis of 4,5-disubstituted 2-aminothiazoles from a,b-unsaturated ketones: Preparation of 5-benzyl-4-methyl-2-aminothiazolium hydrochloride salt"
Org. Syntheses, 2014, 91, 185-200. (Open Access). DOI: 10.15227/orgsyn.091.0185
- Agrawal, S.; Martínez-Castro, E.; Marcos, R.; Martín-Matute, B.
“A readily available ruthenium complex for efficient dynamic kinetic resolution of aromatic α-hydroxy ketones"
Org. Lett. 2014, 6, 2256–2259. (Open Access). DOI: 10.1021/ol500764q
- Bermejo Gómez, A.; Erbing, E.; Batuecas, M.; Vázquez-Romero, A.; Martín-Matute, B.
"Iridium-Catalyzed Isomerization / Bromination of Allylic Alcohols: Synthesis of α-Bromocarbonyl Compounds"
Chem. Eur. J. 2014, 20, 10703-10709. (open access coming soon). DOI: 10.1002/chem.201402350.
Invited article for the special issue "Young Chemists"
Publications 2013
- Pascanu, V.; Yao, Q.; Bermejo Gómez, A.; Gustafsson, Yun, Y.; Wan, W.; Samain, L.; Zou, X.; Martín-Matute, B.
"Sustainable catalysis: Rational Pd loading on MIL-101-NH2 for more efficient and recyclable Suzuki-Miyaura reactions"
Chem. Eur. J. 2013, 19, 17483-17493 (Open Access). DOI: 10.1002/chem.201302621 - Ahlsten, N.; Bermejo Gómez, A.; Martín-Matute, B.
"Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols"
Angew. Chem. Int. Ed. 2013, 52, 6273-6276. (Open Access). DOI: 10.1002/anie.201301013 - Bartoszewicz, A.; Ahlsten, N.; Martín-Matute, B.
"Enantioselective Synthesis of Alcohols and Amines via Iridium-Catalyzed Hydrogenation, Transfer Hydrogenation and Related Processes"
Chem. Eur. J. 2013, 19, 7274-7302. DOI: 10.1002/chem.201202836 - Belén Martín-Matute, Kálmán J. Szabó, Terence N. Mitchell (2013)
"Organotin Reagents in Cross-Coupling Reactions",
in Metal-Catalyzed Cross-Coupling Reactions, Third Edition (eds A. de Meijere F. Diederich, M. Oestreich), Wiley-VCH Verlag GmbH, Weinheim, Germany. Wiley-VCH,(2013). - Stewart, B.; Nyhlen, J.; Martín-Matute, B.; Bäckvall, J.-E.; Privalov, T.
"A computational study of the CO dissociation in cyclopentadienyl ruthenium complexes relevant to the racemization of alcohols"
Dalton Trans. 2013, 42, 927-934. DOI: 10.1039/c2dt31919e
Publications 2012
- B. Martín-Matute, A. Bermejo, N. Ahlsten,
"Method for Preparation of Selective alpha-halogenated allylic carboxyl compounds from allylic alcohols using catalysts"
Patent 2012, P-76116-USP. - Bartoszewicz, A.; Marcos, R.; Sahoo, S.; Inge, A. K.; Zou, X.; Martín-Matute, B.
"A Highly Active Bifunctional Iridium Complex with an Alcohol/Alkoxide-Tethered N-Heterocyclic Carbene for Alkylation of Amines with Alcohols"
Chem. Eur. J. 2012, 18, 14510-14519. (Open Access). DOI: 10.1002/chem.201201845. - Carson, F.; Agrawal, S.; Gustafsson, M.; Bartoszewicz, A.; Moraga, F.; Zou, X.; Martín-Matute, B.
"Ruthenium Complexation in an Aluminium Metal–Organic Framework and its Application in Alcohol Oxidation Catalysis"
Chem. Eur. J. 2012, 18, 15337-15344. DOI: 10.1002/chem.201200885. - Marcos, R.; Martín-Matute, B.
"Combined Enzyme and Transition Metal Catalysis for Dynamic Kinetic Resolutions"
Isr. J. Chem. 2012, 52, 639-652. Invited article. DOI: 10.1002/ijch.201200012 - Agrawal, S.; Lenormand, M.; Martín-Matute, B.
"Selective Alkylation of (Hetero)Aromatic Amines with Alcohols Catalyzed by a Ruthenium Pincer Complex"
Org. Lett. 2012, 14, 1456–1459. (Open Access). DOI: 10.1021/ol3001969 - Ahlsten, N.; Bartoszewicz, A.; Martín-Matute, B.
"Allylic Alcohols as Synthetic Enolate Equivalents: Isomerisation and Tandem Reactions Catalysed by Transition Metal Complexes"
Dalton Trans. 2012, 41, 1660-1670. Article on request for Dalton Transactions, as a Dalton Perspective contribution. DOI: 10.1039/C1DT11678A - Bartoszewicz, A.; Jeżowska, M. M.; Laymand, K.; Möbus, J.; Martín-Matute, B.
"Synthesis of β−Hydroxy and β−Amino Ketones from Allylic Alcohols Catalyzed by η5-(Ph5C5)Ru(CO)2Cl"
Eur. J. Inorg. Chem. 2012, 1517–1530. Article on request for a Special Issue on Organometallic Catalysis DOI: 10.1002/ejic.201101014 - Sahoo, S.; Lundberg, H.; Ahlsten, N.; Edén, M.; Wan, W.; Zou, X.; Martín-Matute, B.
"A Single-site Supported Cationic Rh(I) Complex for Selective Redox Isomerization of Allylic Alcohols"
ChemCatChem, 2012, 4, 243-250. (Open Access). DOI: 10.1002/cctc.201100321
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